Soft Condensed Matter Solutions Manual
Soft matter solutions are made of large solute dissolved in small solvent. The contrast in the size of solute and solvent gives special features to soft matter solutions. This chapter discusses these special features from the general solution theory. It first explains general solution theory for incompressible solutions (an assumption generally made for soft matter) and then considers the relation between free energy of mixing, osmotic pressure, and chemical potentials, followed by a discussion of the conditions for having uniform solutions or phase separated solutions. A model free energy is derived for the lattice model of solutions. Next, two typical soft matter solutions – the polymer solutions and colloidal solutions – are explained. The effect of size difference on osmotic pressure and phase diagrams, and the reason why inter-surface potential is important in colloidal solutions are discussed.
Keywords:free energy, osmotic pressure, incompressible solution, phase separation, spinodal line, critical point, lattice model, polymer solutions, chi-parameter, inter-surface potential
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Jun 20, 2002 The physics of soft condensed matter is probably one of the most 'fashionable' areas in the physical sciences today. This book offers a coherent and clear introduction to the properties and behaviour of soft matter. It begins with a treatment of the general underlying principles: the relation of the structure and dynamics of solids and liquids to intermolecular. Page 2 of 209. Page 3 of 209. Soft Condensed Matter-R.A.L.
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